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selenium monochloride : ウィキペディア英語版
selenium monochloride

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Selenium monochloride is an inorganic compound with the formula Se2Cl2. Although it is called selenium monochloride, a more descriptive name might be diselenium dichloride. It is a reddish-brown, oily liquid that hydrolyses slowly. It exists in chemical equilibrium with SeCl2, SeCl4, chlorine, and elemental selenium. Selenium monochloride is mainly used as a reagent for the synthesis of Se-containing compounds.
==Structure and properties==
Selenium monochloride exhibits C2 molecular symmetry, similar to hydrogen peroxide. The bond length of the Se-Se bond is predicted to be 2.253 Å and the Se-Cl bonds are both 2.227 Å.〔Prascher, Brian P.; Wilson, Angela K. A Computational Study of Dihalogen-μ-Dichalcogenides: XAAX (X = F, Cl, Br; A = S, Se). ''Journal of Molecular Structure''. 2007, ''814'', 1-10.〕
In acetonitrile solutions, it exists in equilibrium with SeCl2 and SeCl4.〔Marc Lamoureux and John Milne "Selenium chloride and bromide equilibria in aprotic solvents; a 77Se NMR study" Polyhedron 1990, Volume 9, pp. 589-595. 〕

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